Morphology controllable synthesis of yttrium oxide-based phosphors from yttrium citrate precursors

稀土学报(英文版), 2011, 29(9): 830-836. doi: 10.1016/S1002-0721(10)60551-0

^1, , ^2, , ^3, , ^4, , ^5, , ^6, , ^7,

1.Key Laboratory of Transparent Opto-Functional Inorganic Materials, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China;Graduate School of Chinese Academy of Sciences, Beijing 100039, China

2.Key Laboratory of Transparent Opto-Functional Inorganic Materials, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China;Graduate School of Chinese Academy of Sciences, Beijing 100039, China

3.Key Laboratory of Transparent Opto-Functional Inorganic Materials, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China

4.Key Laboratory of Transparent Opto-Functional Inorganic Materials, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China

5.Key Laboratory of Transparent Opto-Functional Inorganic Materials, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China

6.Key Laboratory of Transparent Opto-Functional Inorganic Materials, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China

7.Key Laboratory of Transparent Opto-Functional Inorganic Materials, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China

Morphology controllable synthesis of yttrium oxide-based phosphors from yttrium citrate precursors

HUANG Manlian ^1, , GUO Kai ^2, , MAN Zhenyong ^3, , CHEN Haohong ^4, , YANG Xinxin ^5, , XU Fangfang ^6, , ZHAO Jingtai ^7,

3.Key Laboratory of Transparent Opto-Functional Inorganic Materials, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China

4.Key Laboratory of Transparent Opto-Functional Inorganic Materials, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China

5.Key Laboratory of Transparent Opto-Functional Inorganic Materials, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China

6.Key Laboratory of Transparent Opto-Functional Inorganic Materials, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China

7.Key Laboratory of Transparent Opto-Functional Inorganic Materials, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China

Keywords： yttrium oxide

A novel yttrium citrate-templated conversion method for morphology controlled synthesis ofY2O3 microspheres,microflowers and microsheets was reported for the first time.The precursors with controllable morphologies were synthesized with a homogenous precipitation method in aqueous solution without any surfactant.Y2O3 samples with well-preserved morphological architectures were obtained by a subsequent thermal transformation strategy.The chemical formula of the precursor was identified and a two-stage growth mechanism was proposed.The effects of the aging time,reaction temperature,reactant concentration and molar ratio of yttrium nitrate to sodium citrate were discussed.The photoluminescence properties of the Y2O3∶Eu3+ microspheres,microflowers and microsheets prepared were also studied.

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Morphology controllable synthesis of yttrium oxide-based phosphors from yttrium citrate precursors

参考文献