Neodymium ion imprinted polymer (Nd3+-IIP) particles for selective solid-phase extraction of Nd3+ were prepared and determined with inductively coupled plasma atomic emission spectrometry (ICP-AES). The unleached Nd3+-IIP particles were prepared by the copolymerization of Nd3+-5,7-dichloroquinoline-8-ol-4-vinylpyridine ternary complex with styrene and divinyl benzene, then Nd3+ was leached to obtain Nd3+-IIP particles. The adsorption capacity of the Nd3+-IIP was 35.18 mg/g. The largest selectivity coefficient for Nd3+ in the presence of competitive ions such as La3+, Ce3+, Pr3+ and Sm3+ was over 110. The proposed method was validated by analyzing two certified reference materials (GBW07301a sediment and GBW07401 soil) and the determined values were in a good agreement with standard values. The method was convenient, selective, sensitive and applicable to the determination of trace Nd3+ in environmental samples with complicated matrix.
参考文献
[1] | Chang Xijun;Jiang Na;Zheng Hong .Solid-phase extraction of iron(Ⅲ) with an ion-imprinted functionalized silica gel sorbent prepared by a surface imprinting technique[J].Talanta,2007,71:38. |
[2] | Mahmoud M E;Soayed A A;Hafez O F .Selective solid phase extraction and pre-concentration of heavy metals from seawater by physically and chemically immobilize 4-amino-3-hydroxy-2-(2-chlorobenzene)-azo-1-naphthalene ulfonic acid silica gel[J].Microchimica Acta,2003,143:65. |
[3] | Prasada Rao T;Kala R;Daniel S .Metal ion-imprinted polymers-Novel materials for selective recognition of inorganics[J].Analytica Chimica Acta,2006,578:105. |
[4] | Arzu Ersoz;Ridvan Say;Adil Denizli .Ni(II)ion-imprinted solid-phase extraction and preconcentration in aqueous solutions by packed-bed columns[J].Analytica chimica acta,2004(1):91-97. |
[5] | Sibel Buyukiryaki;Ridvan Say;Arzu Ersoz .Selective preconcentration of thorium in the presence of UO22+,Ce3+ and La3+ using Th(IV)-imprinted polymer[J].Talanta,2005,67:640. |
[6] | Kala R;Biju VM;Rao TP .Synthesis, characterization, and analytical applications of erbium(III) ion imprinted polymer particles prepared via gamma-irradiation with different functional and crosslinking monomers[J].Analytica chimica acta,2005(1/2):51-58. |
[7] | Zhang Xinmin,Wu Hao,Zeng Heping,Su Qiang.Luminescent Properties of SrGa2S4:Eu2+ and Its Application in Green-LEDs[J].稀土学报(英文版),2007(06):701-705. |
[8] | Ye Jilei,Li Zengxi,Duan Huachao,Liu Yuan.Lanthanum Modified Ni/γ-Al2O3 Catalysts for Partial Oxidation of Methane[J].稀土学报(英文版),2006(03):302-308. |
[9] | GU Caixiang,LI Qingzhu,GU Zhuoming,ZHU Guangyao.Study on application of CeO2 and CaCO3 nanoparticles in lubricating oils[J].稀土学报(英文版),2008(02):163-167. |
[10] | Yukio Makino,Takashi Yoshioka,Hiromi Nakano,Toshiyuki Ueno,Shoji Miyake.Roles of rare earth oxide additives in millimeter-wave sintering of AlN[J].稀土学报(英文版),2008(02):141-145. |
[11] | Olivier Vigneau;Marc Lemaire;Catherine Pinel .Ionic imprinted resins based on EDTA and DTPA derivatives for lanthanides (III) separation[J].Analytica chimica acta,2001(1):75-82. |
[12] | Regis Garcia;Catherine Pinel;Charles Madic;Marc Lemaire .Ionic imprinting effect in gadolinium/lanthanum separation[J].Tetrahedron Letters,1998,39:8651. |
[13] | Biju V M;Mary Gladis J;Prasada Rao T .Ion imprinted polymer particles:synthesis,characterization and dysprosium ion uptake properties suitable for analytical applications[J].Analytica Chimica Acta,2003,478:43. |
[14] | Zhang Nan;Hu Bin;Huang Chaozhang .A new ion-imprinted silica gel sorbent for on-line selective solid-phase extraction of dysprosium(Ⅲ) with detection by inductively coupled plasma-atomic emission spectrometry[J].Analytica Chimica Acta,2007,597:12. |
[15] | ISO 11466,1995.Soil Quality,Extraction of Trace Elements Soluble in aqua regia[S]. |
[16] | Hu Bin;Chen Da;Su Qingde .Photoacoustic phase study on the frequency dependence of phase angle and triplet state lifetime of Nd(Ⅲ)-acetylacetonate[J].Spectrochimica Acta Part A:Molecular and Biomolecular Spectroscopy,2006,63:55. |
[17] | Yang Y T;Zhang S Y;Su Q D .Photoacoustic spectroscopy study on the co-luminescence phenomena of solid rare earth complexes[J].Materials Research Bulletin,2005,40:1010. |
[18] | 于锡娟,伍荣护,宋慧宇,苏庆德.Study on Dihydrated Praseodymium Acetylacetonate by Photoacoustic Spectra with Broad Wavelength Range[J].稀土学报(英文版),2003(02):135-138. |
[19] | Crosby R;Whan R;Alive R .Intramolecular energy transfer in rare earth chelates:role of the triplet State[J].Journal of Chemical Physics,1961,34:743. |
[20] | Kala R;Mary Gladis J;Prasada Rao T .Preconcentrative separation of erbium from Y,Dy,Ho,Tb and Tm by using ion imprinted polymer particles via solid phase extraction[J].Analytica Chimica Acta,2004,518:143. |
[21] | Ozgen Saatcilar;Nuray Satiroglu;Ridvan Say .Binding behavior of Fe3+ ions on ion-imprinted polymeric beads for analytical applications[J].Journal of Applied Polymer Science,2006,101:3520. |
[22] | Fish R H.ACS symposium series 703[M].Washington,DC:American Chemical Society,1998:238. |
[23] | Vigneau O;Pinel C;Lemaire M .Solid-liquid separation of lanthanide/lanthanide and lanthanide/actinide using ionic imprinted polymer based on a DTPA derivative[J].Chemistry Letters,2002,31:202. |
[24] | Gupta R D;Manku S;Bhat A N .Determination of the stability constants of lanthanon(Ⅲ) complexes with 8-hydroxyquinoline and some of its 5,7-disubstituted derivatives[J].Journal of THE LESS-COMMON METALS,1970,20:345. |
[25] | Daniel MacDougall;Warren Crummett B .Guidelines for data acquisition and data quality evaluation in environmental chemistry[J].Analytical Chemistry,1980,52:2242. |
[26] | Long G L;Voigtman E G;Kosinski M A .Reduction of electronic noise in inductively coupled plasma atomic emission and fluorescence spectrometric measurements[J].Analytical Chemistry,1983,55:1432. |
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