Synthesis of A Novel UV-curable Oligmer 1,4-cyclohexanedimethanol Glycidyl Ether Acrylate and Study on Its UV-curing Properties

武汉理工大学学报-材料科学版(英文版), 2014, (6): 1283-1289. doi: 10.1007/s11595-014-1082-5

HUANG Biwu ^1, , DENG Chong ^2, , XU Qinchang ^3, , CHEN Weiqing ^4, , ZOU Huaihua ^5,

1.School of Materials Science and Engineering, Nanchang University, Nanchang 330031, China

2.School of Materials Science and Engineering, Nanchang University, Nanchang 330031, China

3.School of Materials Science and Engineering, Nanchang University, Nanchang 330031, China

4.School of Materials Science and Engineering, Nanchang University, Nanchang 330031, China

5.School of Materials Science and Engineering, Nanchang University, Nanchang 330031, China

基金项目: the Natural Science Foundation of Jiangxi Province(20142BAB206029)

Synthesis of A Novel UV-curable Oligmer 1,4-cyclohexanedimethanol Glycidyl Ether Acrylate and Study on Its UV-curing Properties

Keywords： 1,4-cyclohexanedimethanol glycidyl ether acrylate

A novel UV-curable oligmer 1,4-cyclohexanedimethanol glycidyl ether acrylate (CHDMGEA) was synthesized by utilizing 1,4-cyclohexanedimethanol glycidyl ether (CHDMGE) and acrylic acid (AA) as starting materials, triphenyl phosphine as catalyst and p-hydroxyanisole as inhibitor. The optimum synthetic conditions were that the concentration of triphenyl phosphine was 0.90%of reactants by weight, the concentration of p-hydroxyanisole was 0.20%of reactants by weight, the reaction temperature was 90-100℃, and the molar ratio of CHDMGE to AA was 0.5:1.1. The experimental results show that CHDMGEA is a kind of good UV-curable oligmer. The impact resistance of the UV-cured films with CHDMGEA as oligmer to prepare UV-curing coating was superior to that of the UV-cured films with bisphenol A diglycidyl ether diacrylate (BPGEA) as oligmer to prepare UV-curing coating.

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材料期刊网

Synthesis of A Novel UV-curable Oligmer 1,4-cyclohexanedimethanol Glycidyl Ether Acrylate and Study on Its UV-curing Properties

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