The bacterial cellulose prepared by ourselves was used in the adsorption of Cr(Ⅵ).The effects of performance parameters such as adsorption time,pH,the adsorbent dosage on Cr(Ⅵ) were investigated.Results showed that pH was a very important parameter to the adsorbed efficiency.Removal rate of Cr(Ⅵ)approached to 15% under the condition of pH 1.5,adsorbent dosage 1.0 g-L-1 and co(initial concentration of Cr)50 mg·L-1.The saturated monolayer adsorption quantity was 5.13 mg/g dry BC.The adsorption rate could be well fitted by pseudo-second rate model,adsorption isotherm could be described by Langmuir model,and they have good linear.Typical single-molecule layer adsorption of bacterial cellulose for Cr(Ⅵ) could be descripted and electrostatic force was one of the main sorption mechanisms.HCl can desorb the Cr(Ⅵ) from the adsorbent effectively.
参考文献
[1] | M. Nasiruddin Khan;M. Farooq Wahab .Characterization of chemically modified corncobs and its application in the removal of metal ions from aqueous solution[J].Journal of hazardous materials,2007(1):237-244. |
[2] | 王九思,来风习,韩迪,张鹏会.超声波-铁氧体法处理含镍废水实验研究[J].广州化工,2009(08):193-195. |
[3] | 范力,张建强,程新,刘伟,夏明芳,王志良.离子交换法及吸附法处理含铬废水的研究进展[J].水处理技术,2009(01):30-33. |
[4] | Nada AMA;El-Wakil NA;Hassan ML;Adel AM .Differential adsorption of heavy metal ions by cotton stalk cation-exchangers containing multiple functional groups[J].Journal of Applied Polymer Science,2006(6):4124-4132. |
[5] | 邹瑜,陈仕艳,王静芸,石帅科,颜志勇,王华平.细菌纤维素吸附Cu2+的研究[J].材料科学与工程学报,2008(03):426-429. |
[6] | 鲁敏,李彦英,关晓辉,魏德洲.细菌纤维素的制备及其吸附Cd2+的研究[J].东北大学学报(自然科学版),2010(08):1196-1199. |
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