In order to improve the electrochemical performance and thermal stability of Li1.05Co1/3Ni1/3Mn1/3O2 materials,Li1.05Co0.3 Ni0.35Mn0.3M0.05O2(M=Ge,Sn) cathode materials were synthesized via co-precipitation method.The structure,electrochemical performance and thermal stability were characterized by X-ray diffraction(XRD),charge/discharge cycling,cyclic voltammetry(CV),electrochemical impedance spectroscopy(EIS) and differential scanning calorimetry(DSC).ESEM showed that Sn-doped and Ge-doped slightly increased the size of grains.XRD and CV showed that Sn-doped and Ge-doped powders were homogeneous and had the better layered structure than the bare one.Sn-doped and Ge-doped improved high rate discharge capacity and cycle-life performance.The reason of the better cycling performance of the doped one was the increasing of lithium-ion diffusion rate and charge transfer rate.Sn-doped and Ge-doped also improved the mateials thermal stability.
参考文献
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