Preparation of Cyclodextrin-Based Carbonaceous Catalyst and Its Application in the Esterification

武汉理工大学学报-材料科学版(英文版), 2011, 26(3): 455-458. doi: 10.1007/s11595-011-0248-7

^1, , ^2,

1.Department of Environmental and Chemical Engineering,Shanghai University,Shanghai 200444,China;Department of Automation Science,Guangdong Polytechnic Normal University,Guangzhou 510665,China

2.Department of Environmental and Chemical Engineering,Shanghai University,Shanghai 200444,China

基金项目: Funded by the Guangdong Science Project(2008B011000015)

Preparation of Cyclodextrin-Based Carbonaceous Catalyst and Its Application in the Esterification

SHAN Chun ^1, , QIAN Guangren ^2,

1.Department of Environmental and Chemical Engineering,Shanghai University,Shanghai 200444,China;Department of Automation Science,Guangdong Polytechnic Normal University,Guangzhou 510665,China

2.Department of Environmental and Chemical Engineering,Shanghai University,Shanghai 200444,China

Keywords： β-Cyclodextrin

A new carbonaceous catalyst with sulfonic acid group (-SO3H) was prepared by incomplete carbonization of β-cyclodextrin followed by sulfonation. The sulfonated amorphous carbon was characterized by IR, elemental analysis, DSC-TGA and PXRD, and the catalytic activity was investigated to be an efficient catalyst for the esterification reactions with maximum yield of 87%. The sulfonated carbonaceous catalyst was readily separated from the reaction solution and keeps approximately equal catalytic activity. The results confirm that the active centre is the hydrophilic sulfonic acid functional group in the esterification reactions.

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材料期刊网

Preparation of Cyclodextrin-Based Carbonaceous Catalyst and Its Application in the Esterification

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