Determination of Trace Elements in High Purity Gold by High Resolution Inductively Coupled Plasma Mass Spectrometry

武汉理工大学学报-材料科学版(英文版), 2009, 24(4): 608-612. doi: 10.1007/s11595-009-4608-5

^1, , ^2, , ^3, , ^4,

1.School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China;Department of Chemistry, Hunan Institute of Technology, Hengyang 421008, China

2.School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China

3.School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China;Department of Chemistry, Hunan Institute of Technology, Hengyang 421008, China

4.College of Chemistry and Chemical Engineering, Nanhua University, Hengyang 410001, China

基金项目: the Hunan Provincial Natural Science Foundation of China(05JJ40017) Hunan Provincial Education Department of China(07C029,08C260)

Determination of Trace Elements in High Purity Gold by High Resolution Inductively Coupled Plasma Mass Spectrometry

XIE Hualin ^1, , HUANG Kelong ^2, , NIE Xidu ^3, , FU Liang ^4,

1.School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China;Department of Chemistry, Hunan Institute of Technology, Hengyang 421008, China

2.School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China

3.School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China;Department of Chemistry, Hunan Institute of Technology, Hengyang 421008, China

4.College of Chemistry and Chemical Engineering, Nanhua University, Hengyang 410001, China

Keywords： high purity gold

Trace elements were determined in high purity gold by high resolution inductively coupled plasma mass spectrometry(HR-ICP-MS).Sample were decomposed by aqua regia.To overcome some potentially problematic spectral interference,measurements were acquired in both medium and high resolution modes.The matrix effects due to the presence of excessive HCl and Au were evaluated.The optimum conditions for the determination was tested and discussed.The standard addition method was employed for quantitative analysis.The detection limits range from 0.01 μg/g to 0.28 μg/g depending on the elements.The method is accurate,quick and convenient.It has been applied to the determination of trace elements in high purity gold with satisfactory results.

参考文献

[1]	I.Karakjova;S.Arpadjan;L.Jordanova .Determination of trace metals in high purity gold[J].Fresenius' Journal of Analytical Chemistry,2000(2):146-150.
[2]	Sung-Min Choi;Gae-Ho Lee;Jae-Kil Han .Determination of Trace Elements of Ge and P in a Gold Bonding Wire by Inductively Coupled Plasma Atomic Emission Spectrometry[J].Bulletin of the Korean Chemical Society,2008(2):393-397.
[3]	Sun YC.;Lin TS.;Wen JC.;Hsieh CH. .Determination of trace impurities in high purity gold by inductively coupled plasma mass spectrometry with prior matrix removal by electrodeposition[J].Spectrochimica Acta, Part B. Atomic Spectroscopy,2000(9):1481-1489.
[4]	Kulkarni MJ.;Mathur JN.;Page AG.;Argekar AA. .Chemical separation and inductively coupled plasma-atomic emission spectrometric determination of seventeen trace metals in thorium oxide matrix using a novel extractant - Cyanex-923[J].Analytica chimica acta,1998(2/3):163-171.
[5]	C.Billing;D.R.Groot;J.F.van Staden .Determination of arsenic in gold samples using matrix exchange differential pulse stripping voltammetry[J].Analytica chimica acta,2002(2):201-208.
[6]	Hualin XIE;Xidu NIE .Determination of Trace Impurities in High-Purity Cadmium by High-Resolution Inductively Coupled Plasma Mass Spectrometry[J].Analytical Sciences: The International Journal of The Japan Society for Analytical Chemistry,2006(10):1371-1374.
[7]	XIE Hualin,NIE Xidu,LI Libo,SONG Chuhua.Direct Determination of Trace Impurities in High Purity Zinc Oxide by High Resolution Inductively Coupled Plasma Mass Spectrometry[J].武汉理工大学学报（材料科学版）英,2006(02):28-32.
[8]	Nakane K.;Morikawa H.;Tsuge A.;Ishizuka T.;Uwamino Y. .Determination of trace impurities in high-purity aluminium oxide by high resolution inductively coupled plasma mass spectrometry[J].Analytica chimica acta,1998(1/2):79-85.
[9]	XIE Hualin,HUANG Kelong,NIE Xidu,TANG Yougen.Quantification of trace amounts of impurities in high purity cobalt by high resolution inductively coupled plasma mass spectrometry[J].稀有金属（英文版）,2007(03):286-291.
[10]	Rodushkin I.;Ruth T. .DETERMINATION OF TRACE METALS IN ESTUARINE AND SEA-WATER REFERENCE MATERIALS BY HIGH RESOLUTION INDUCTIVELY COUPLED PLASMA MASS SPECTROMETRY[J].Journal of Analytical Atomic Spectrometry,1997(10):1181-1185.

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Determination of Trace Elements in High Purity Gold by High Resolution Inductively Coupled Plasma Mass Spectrometry

参考文献