机械工程材料, 2017, 41(1): 34-42.
10.11973/jxgccl201701007
基于植物模板法制备高性能石墨烯/氧化锰复合材料及其电化学性能
何凤娟
1,
,
钱君超
2,
,
刘成宝
3,
,
陈志刚
4,
,
李萍
5,
1.苏州科技学院化学生物与材料工程学院，江苏省环境功能材料重点实验室，苏州 215009;
2.苏州科技学院化学生物与材料工程学院，江苏省环境功能材料重点实验室，苏州 215009;
3.苏州科技学院化学生物与材料工程学院，江苏省环境功能材料重点实验室，苏州 215009;
4.苏州科技学院化学生物与材料工程学院，江苏省环境功能材料重点实验室，苏州 215009;
5.苏州科技学院化学生物与材料工程学院，江苏省环境功能材料重点实验室，苏州 215009
以植物膜作为碳源和模板,通过浸渍氯化锰溶液并经两次煅烧合成了石墨烯/氧化锰复合材料,分析了该复合材料的微观形貌、物相组成以及表面性能；将该复合材料制成电极,通过循环伏安和恒流充放电方法测试了其电化学性能.结果表明：石墨烯/氧化锰复合材料中不存在氧化石墨烯,其石墨烯为褶皱状片层结构,厚度约1．449 nm,其上负载着大量粒径为10~40 nm的氧化锰颗粒；该复合材料的BET比表面积约为202．5 m2?g－1,孔径分布于5~30 nm；该复合材料的电化学反应可逆性优良,比电容为245 F?g－1,远高于市购碳粉(25~26 F?g－1)和植物膜煅烧制备石墨烯(45~50 F?g－1)的.
参考文献：
[1] Patil, Swati J.;Patil, Bebi H.;Bulakhe, Ravindra N.;Lokhande, Chandrakant D..Electrochemical performance of a portable asymmetric supercapacitor device based on cinnamon-like La2Te3 prepared by a chemical synthesis route[J].RSC Advances,201499(99):56332-56341.
[2] Montree Sawangphruk;Montakan Suksomboon;Kawita Kongsupornsak.High-performance supercapacitors based on silver nanoparticle-polyaniline-graphene nanocomposites coated on flexible carbon fiber paper[J].Journal of Materials Chemistry, A. Materials for energy and sustainability,201334(34):9630-9636.
[3] 付猛;岳艳娟;祝雅娟;陈志刚.水热法制备石墨烯及其表征[J].机械工程材料,2013(6):84-88.
[4] Fan Zhang;Tengfei Zhang;Xi Yang;Long Zhang;Kai Leng;Yi Huang;Yongsheng Chen.A high-performance supercapacitor-battery hybrid energy storage device based on graphene-enhanced electrode materials with ultrahigh energy density[J].Energy & environmental science: EES,20135(5):1623-1632.
[5] Dongbo Yu;Jianfeng Yao;Ling Qiu.In situ growth of Co3O4 nanoparticles on α-MnO2 nanotubes: a new hybrid for high-performance supercapacitors[J].Journal of Materials Chemistry, A. Materials for energy and sustainability,201422(22):8465-8471.
[6] Zhu, Yirong;Wu, Zhibin;Jing, Mingjun;Hou, Hongshuai;Yang, Yingchang;Zhang, Yan;Yang, Xuming;Song, Weixin;Jia, Xinnan;Ji, Xiaobo.Porous NiCo2O4 spheres tuned through carbon quantum dots utilised as advanced materials for an asymmetric supercapacitor[J].Journal of Materials Chemistry, A. Materials for energy and sustainability,20152(2):866-877.
[7] 付猛;张婷婷;龚利云;陈志刚.化学分散法制备少数层石墨烯及其表征[J].机械工程材料,2011(12):89-92,96.
[8] He, Y.;Chen, W.;Li, X.;Zhang, Z.;Fu, J.;Zhao, C.;Xie, E..Freestanding three-dimensional graphene/Mno_2 composite networks as ultralight and flexible supercapacitor electrodes[J].ACS nano,20131(1):174-182.
[9] Ding YS;Shen XF;Gomez S;Luo H;Aindow M;Suib SL.Hydrothermal growth of manganese dioxide into three-dimensional hierarchical nanoarchitectures[J].Advanced functional materials,20064(4):549-555.
[10] Hyuck Lee;Junmo Kang;Mi Suk Cho.MnO2/grapheee composite electrodes for supercapacitors: the effect of graphene Intercalation on capacitance[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,201145(45):18215-18219.
[11] Zhibin Lei;Jintao Zhang;X. S. Zhao.Ultrathin MnO2 nanofibers grown on graphitic carbon spheres as high-performance asymmetric supercapacitor electrodes[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,20121(1):153-160.
[12] Na Li;Minhua Cao;Changwen Hu.Review on the latest design of graphene-based inorganic materials[J].Nanoscale,201220(20):6205-6218.
材料期刊网