为研究p型材料和n型材料复合时气敏特性的变化,采用静电纺丝法分别制备了CuO、SnO2以及3种比例混合的CuO/SnO2复合纳米纤维材料,并通过XRD及SEM对其形貌、微观结构等进行表征。测试了该5种材料对丙酮、甲醛、甲醇、乙醇、甲苯等VOC气体的敏感特性。研究表明,CuO/SnO2=2∶1的复合材料对丙酮、甲苯和乙醇的的响应值有一定提高;CuO/SnO2=1∶1的复合材料对丙酮具有很高响应的同时,对乙醇和甲苯的响应产生了一定的抑制作用,从而大大提高了材料的选择性。其机理是:半导体材料复合后,在复合材料的表面会有更多的氧吸附,导致更多的VOC气体在半导体材料表面发生反应,使材料的电阻值变化更加明显,提高了材料的响应值。
参考文献:
[1] 张成芬.室内甲醛污染的危害及测定方法的研究[J].化学教学,2007(01):8-10.
[2] Mccue JT;Ying JY.SnO2-In2O3 nanocomposites as semiconductor gas sensors for CO and NOx detection[J].Chemistry of Materials: A Publication of the American Chemistry Society,20075(5):1009-1015.
[3] Lili Wang;Zheng Lou;Rui Wang.Ring-like PdO-MO with lamellar structure for gas sensor application[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,201225(25):12453-12456.
[4] Song XF;Wang ZJ;Liu YB;Wang C;Li LJ.A highly sensitive ethanol sensor based on mesoporous ZnO-SnO2 nanofibers[J].Nanotechnology,20097(7):75501-1-75501-5-0.
[5] Devi GS.;Rao VJ.;Manorama S..GAS SENSITIVITY OF SNO2/CUO HETEROCONTACTS[J].Journal of the Electrochemical Society,19958(8):2754-2757.
[6] Lee, Jae-Hyoung;Katoch, Akash;Choi, Sun-Woo;Kim, Jae-Hun;Kim, Hyoun Woo;Kim, Sang Sub.Extraordinary Improvement of Gas-Sensing Performances in SnO2 Nanofibers Due to Creation of Local p-n Heterojunctions by Loading Reduced Graphene Oxide Nanosheets[J].ACS applied materials & interfaces,20155(5):3101-3109.
[7] Tamaki J.;Yamada Y.;Yamamoto Y.;Miura N.;Yamazoe N.;Shimanoe K..Dilute hydrogen sulfide sensing properties of CuO-SnO2 thin film prepared by low-pressure evaporation method[J].Sensors and Actuators, B. Chemical,19981/2(1/2):121-125.
[8] Gun-Joo Sun;Sun-Woo Choi;Akash Katoch.Bi-functional mechanism of H2S detection using CuO-SnO2 nanowiresf[J].Journal of Materials Chemistry, C. materials for optical and electronic devices,201335(35):5454-5462.
[9] Hu Y.;Zhou XH.;Han Q.;Cao QX.;Huang YX..Sensing properties of CuO-ZnO heterojunction gas sensors[J].Materials Science & Engineering, B. Solid-State Materials for Advanced Technology,20031/3(1/3):41-43.
[10] Wang, X.;Wang, W.;Li, H.;Fu, C.;Ke, Y.;He, S..Development of a SnO _2/CuO-coated surface acoustic wave-based H _2S sensor with switch-like response and recovery[J].Sensors and Actuators, B. Chemical,20121(1):10-16.
[11] Choi, S.-W.;Katoch, A.;Zhang, J.;Kim, S.S..Electrospun nanofibers of CuO-SnO_2 nanocomposite as semiconductor gas sensors for H_2S detection[J].Sensors and Actuators, B. Chemical,2013:585-591.
[12] Wang, L.;Kang, Y.;Wang, Y.;Zhu, B.;Zhang, S.;Huang, W.;Wang, S..CuO nanoparticle decorated ZnO nanorod sensor for low-temperature H _2S detection[J].Materials science & engineering, C. Biomimetic and supramolecular systems,20127(7):2079-2085.
[13] 陈伟根;李倩竹;徐苓娜;彭尚怡;刘军.CuO-SnO2纳米传感器的H2检测特性研究[J].仪器仪表学报,2013(10):2244-2250.
[14] Ding, X.;Zeng, D.;Xie, C..Controlled growth of SnO_2 nanorods clusters via Zn doping and its influence on gas-sensing properties[J].Sensors and Actuators, B. Chemical,20102(2):336-344.
[15] 何琴;黄保军;李颖颖;法文君.生物模板法制备微纳米二氧化锡[J].化工新型材料,2012(5):151-153.
[16] Zhang Y;He XL;Li JP;Miao ZJ;Huang F.Fabrication and ethanol-sensing properties of micro gas sensor based on electrospun SnO2 nanofibers[J].Sensors and Actuators, B. Chemical,20081(1):67-73.
[17] 贾锐军;彭同江;孙红娟;刘海峰.SnO2纳米薄膜的溶胶-凝胶法制备及气敏性能[J].化工新型材料,2008(1):15-16,30.
[18] Hyo-Joong Kim;Jong-Heun Lee.Highly sensitive and selective gas sensors using p-type oxide semiconductors: Overview[J].Sensors and Actuators, B. Chemical,2014:607-627.
[19] 唐伟;王兢.金属氧化物异质结气体传感器气敏增强机理[J].物理化学学报,2016(5):1087-1104.