人工晶体学报, 2017, 46(1): 63-68.
采用稻壳和酚醛树脂作为复合碳源,无水四氯化锆和正硅酸乙酯为原料,氟化锂为矿化剂,通过非水解溶胶-凝胶法制备了C@ZrSiO4黑色包裹色料。分别利用X射线衍射( XRD)和透射电子显微镜( TEM)分析了色料的晶体结构和显微形貌,同时采用CIE-L? a? b?色度仪表征了样品的色度值。实验结果表明,酚醛树脂可以同时作为碳源和稻壳的分散剂,并且酚醛树脂和稻壳作为复合碳源制备的包裹黑色色料的发色效果优于使用单一碳源(稻壳或者酚醛树脂)制备的色料。当复合碳源添加量为硅酸锆2.50wt%时(其中酚醛树脂添加量为稻壳的15wt%),经1000℃氮气气氛热处理1 h后,可以制备出呈色良好的C@ZrSiO4黑色色料,色度值L?=39.02,a?=1.14,b?=2.68。
引用：
张筱君,
潘婷,
江伟辉,
陈婷,
刘健敏,
徐彦乔
复合碳源对C@ZrSiO4色料合成及色度的影响.
人工晶体学报,
2017, 46(1): 63-68.
doi:
参考文献：
[1] Claudio Caselli;Gigliola Lusvardi;Gianluca Malavasi.Multitechnique approach to V-ZrSiO_4 pigment characterization and synthesis optimization[J].Journal of the European Ceramic Society,20072/3(2/3):1743-1750.
[2] M. Cannio;F. Bondioli.Mechanical activation of raw materials in the synthesis of Fe_2O_3-ZrSiO_4 inclusion pigment[J].Journal of the European Ceramic Society,20123(3):643-647.
[3] 宋晓岚;彭林;丁意;李媚;王顺葵;屈一新;邱冠周.ZSiO4/Cd（S1-xSex）包裹色料的水热合成[J].硅酸盐学报,2009(7):1264-1267.
[4] 彭诚;张楚鑫;吕明;李智鸿;吴建青.共沉淀法制备硅酸锆包裹炭黑及其高温稳定性[J].无机材料学报,2013(8):847-852.
[5] 朱振峰;余唯杰;李晖;朱敏;马建中.微乳液法制备包裹型锆铁红陶瓷颜料[J].硅酸盐学报,2006(11):1331-1334.
[6] Qibing Chang;Xia Wang;Yongqing Wang.Encapsulated carbon black prepared by sol-gel-spraying: A new black ceramic pigment[J].Journal of the European Ceramic Society,201413(13):3151-3157.
[7] Feng Zhao;Weidong Li;Hongjie Luo.Sol-gel modified method for obtention of gray and pink ceramic pigments in zircon matrix[J].Journal of Sol-Gel Science and Technology,20092(2):247-252.
[8] Jiang, Weihui;Xu, Xiayi;Chen, Ting;Liu, Jianmin;Zhang, Xiaojun.Preparation and chromatic properties of C@ZrSiO4 inclusion pigment via non-hydrolytic sol gel method[J].Dyes and Pigments,2015:55-59.
[9] 张筱君;陈婷;江伟辉;刘健敏;查剑锐.复合包裹法制备C@SiO2@ZrSiO4黑色色料的研究[J].陶瓷学报,2016(1):17-22.
[10] Sae-oui P.;Rakdee C.;Thanmathorn P..Use of rice husk ash as filler in natural rubber vulcanizates: In comparison with other commercial fillers[J].Journal of Applied Polymer Science,200211(11):2485-2493.
[11] Sirarat Kongwudthiti;Piyasan Praserthdam;Waraporn Tanakulrungsank.The influence of Si-O-Zr bonds on the crystal-growth inhibition of zirconia prepared by the glycothermal method[J].Journal of Materials Processing Technology,20031/3(1/3):186-189.
[12] 李小红;江伟辉;魏恒勇;喻佑华;宋福生.金属氯化醇盐的红外光谱分析[J].广州化学,2008(4):42-47.
[13] 陈智琴;刘洪波;何月德;陈鸯飞.高残炭率酚醛树脂的耐热性能研究[J].工程塑料应用,2006(11):56-60.
[14] 张杰;黄玉东;刘丽;张志谦;杨小波.超声处理对酚醛树脂及纳米分散的影响[J].航空材料学报,2005(5):42-45.
材料期刊网