人工晶体学报, 2017, 46(1): 50-54.
CoO/NiO/CoNi复合材料的制备及其储锂性能的研究
刘焕
1,
,
王昕璐
2,
,
王进贤
3,
,
于文生
4,
,
杨颖
5,
,
张洪波
6,
,
董相廷
7,
1.长春理工大学化学与环境工程学院，应用化学与纳米技术吉林省高校重点实验室，长春130022;
2.长春理工大学化学与环境工程学院，应用化学与纳米技术吉林省高校重点实验室，长春130022;
3.长春理工大学化学与环境工程学院，应用化学与纳米技术吉林省高校重点实验室，长春130022;
4.长春理工大学化学与环境工程学院，应用化学与纳米技术吉林省高校重点实验室，长春130022;
5.长春理工大学化学与环境工程学院，应用化学与纳米技术吉林省高校重点实验室，长春130022;
6.长春理工大学化学与环境工程学院，应用化学与纳米技术吉林省高校重点实验室，长春130022;
7.长春理工大学化学与环境工程学院，应用化学与纳米技术吉林省高校重点实验室，长春130022
将Al72 Ni13.4 Co14.6十次准晶作为前驱体合金,通过去合金化法制备了CoO/NiO/CoNi微纳复合材料作为锂离子电池负极材料。采用X射线衍射( XRD)、扫描电镜( SEM)等材料结构分析方法对产物进行表征。通过恒电流充放电技术研究该电极材料的电化学性能,结果表明,在200 mA·g-1电流密度下,首次充放电容量为417 mAh·g-1和617 mAh·g-1,库伦效率为67.6%,经过500圈循环后放电容量仍保持为585 mAh·g-1,表现出良好的循环性能。
引用：
刘焕,
王昕璐,
王进贤,
于文生,
杨颖,
张洪波,
董相廷
CoO/NiO/CoNi复合材料的制备及其储锂性能的研究.
人工晶体学报,
2017, 46(1): 50-54.
doi:
参考文献：
[1] Hao Bin Wu;Jun Song Chen;Huey Hoon Hng.Nanostructured metal oxide-based materials as advanced anodes for lithium-ion batteries[J].Nanoscale,20128(8):2526-2542.
[2] Dongdong Li;Liang-Xin Ding;Suqing Wang.Ultrathin and highly-ordered CoO nanosheet arrays for lithium-ion batteries with high cycle stability and rate capability[J].Journal of Materials Chemistry, A. Materials for energy and sustainability,201416(16):5625-5630.
[3] B. Phung Ngoc;C. Geantet;J. A. Dalmon.Quasicrystalline Structures as Catalyst Precursors for Hydrogenation Reactions[J].Catalysis Letters,20091/2(1/2):59-69.
[4] Limin Wang;Liqun Ma;Chaoli Ma.Formations of amorphous and quasicrystal phases in Ti-Zr-Ni-Cu alloys[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,20031/2(1/2):234-240.
[5] Feng Li;Qing-Qing Zou;Yong-Yao Xia.CoO-loaded graphitable carbon hollow spheres as anode materials for lithium-ion battery[J].Journal of Power Sources,20082(2):546-552.
[6] Yongming Sun;Xianluo Hu;Wei Luo.Self-assembled mesoporous CoO nanodisks as a long-life anode material for lithium-ion batteries[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,201227(27):13826-13831.
[7] Sun, Xiaolei;Si, Wenping;Liu, Xianghong;Deng, Junwen;Xi, Lixia;Liu, Lifeng;Yan, Chenglin;Schmidt, Oliver G..Multifunctional Ni/NiO hybrid nanomembranes as anode materials for high-rate Li-ion batteries[J].Nano Energy,2014:168-175.
材料期刊网