{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"在微波辐射和无催化剂条件下,由吡啶2,6-二甲酸与乙二胺反应合成了2,6-二(2′-咪唑啉-2′-基)吡啶(L),采用常规加热法合成其<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>[CrL2][NO3]3. 用核磁共振、红外光谱、元素分析、热重分析和摩尔电导率测试技术对其进行表征分析. 通过紫外吸收光谱和黏度测试,分别考察了配体及<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>与DNA的键合常数及其作用方式. 结果表明,配体L以氢键和沟面作用方式与DAN键合,而<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>以氢键和静电作用模式与DNA键合. 密度泛函理论(DFT)计算结果较好的解释了L及[CrL2]3+与DNA的相互作用模式.","authors":[{"authorName":"张金艳","id":"4cc0c8fd-0b06-4274-b935-89def154e0c1","originalAuthorName":"张金艳"},{"authorName":"肖小明","id":"5d6d231a-b29a-4591-b2fd-b11844c5647b","originalAuthorName":"肖小明"},{"authorName":"蒋艳","id":"f5122430-04e5-483a-8363-91b60303d744","originalAuthorName":"蒋艳"},{"authorName":"谭年元","id":"ee024dbb-0ec7-463e-971d-d6f3c109fb95","originalAuthorName":"谭年元"}],"doi":"10.3724/SP.J.1095.2010.90729","fpage":"1032","id":"3e24347e-fa12-4b04-bf4d-bbfa6fb34ed0","issue":"9","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"c800eeca-9f13-4d59-9e07-569790d2af90","keyword":"二(咪唑啉基)吡啶","originalKeyword":"二(咪唑啉基)吡啶"},{"id":"18df229d-7d97-482e-ac0b-6a321b54c2f4","keyword":"<span style=\"color:red\">铬</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>","originalKeyword":"铬配合物"},{"id":"b218cc99-6506-460b-9b3f-7d616fbb21c4","keyword":"DNA","originalKeyword":"DNA"},{"id":"73b03833-8721-494b-9ba4-4547a488a06c","keyword":"微波辐射","originalKeyword":"微波辐射"},{"id":"edd00409-59a0-4299-a64f-eb7d4bb05bf1","keyword":"DFT","originalKeyword":"DFT"}],"language":"zh","publisherId":"yyhx201009009","title":"2,6-二(2′-咪唑啉-2′-基)吡啶合<span style=\"color:red\">铬</span>(Ⅲ)的合成及其与DNA的相互作用","volume":"27","year":"2010"},{"abstractinfo":"通过酒石酸钾钠、单宁酸、乙醇、甲醇四种还原剂还原Cr(Ⅵ)获得Cr(Ⅲ)<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>.通过盐雾试验、电化学试验研究了四种不同Cr(Ⅲ)<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>对三价<span style=\"color:red\">铬</span>钝化液性能的影响.结果表明:不同Cr(Ⅲ)<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>钝化出的产品,具有不同的耐腐蚀性能,其中酒石酸钾钠还原的Cr(Ⅲ)<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>钝化液性能最好;Cr(Ⅲ)<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>对三价<span style=\"color:red\">铬</span>钝化液性能起着最主要的作用.","authors":[{"authorName":"陈小平","id":"ab8fd528-38d3-4e40-90ed-aa9691575027","originalAuthorName":"陈小平"},{"authorName":"潘剑锋","id":"b4f802bc-4eed-404b-b2d4-0c94fc5b2d36","originalAuthorName":"潘剑锋"},{"authorName":"赵栋梁","id":"74d7c836-a58d-4801-807d-2ca5267d37c4","originalAuthorName":"赵栋梁"},{"authorName":"高志强","id":"520a7e36-27b3-44e5-a8a1-7e70a2067947","originalAuthorName":"高志强"},{"authorName":"王向东","id":"ba116e98-70d8-4d7e-9287-acc931793c5f","originalAuthorName":"王向东"}],"doi":"","fpage":"33","id":"498cd788-d6eb-443c-ad75-84e7569ae379","issue":"5","journal":{"abbrevTitle":"CLBH","coverImgSrc":"journal/img/cover/CLBH.jpg","id":"7","issnPpub":"1001-1560","publisherId":"CLBH","title":"材料保护"},"keywords":[{"id":"54c60514-f9fa-47cf-9f65-6d5dcf2a67dd","keyword":"镀锌层","originalKeyword":"镀锌层"},{"id":"beac454b-9677-47d9-91fb-ab5ce88838df","keyword":"三价<span style=\"color:red\">铬</span>钝化","originalKeyword":"三价铬钝化"},{"id":"2a786fce-5d16-483c-833f-ec69ee9fd4ca","keyword":"Cr(Ⅲ)<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>","originalKeyword":"Cr(Ⅲ)配合物"},{"id":"3b96afae-077b-45d7-a0b2-5661fb77e0c3","keyword":"钝化液","originalKeyword":"钝化液"},{"id":"92c2bace-a337-4d90-9511-c090924b3a9b","keyword":"耐蚀性能","originalKeyword":"耐蚀性能"}],"language":"zh","publisherId":"clbh200805010","title":"不同Cr(Ⅲ)<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>对三价<span style=\"color:red\">铬</span>钝化液性能的影响","volume":"41","year":"2008"},{"abstractinfo":"通过氧化和超声波分散制备了氧化石墨烯(GO)纳米片层分散液,再与重铬酸钾进行氧化还原反应制备 GO-Cr (Ⅲ)<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>,应用 FT-IR 和 AFM 对GO-Cr(Ⅲ)<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>和 GO 纳米片层进行了表征.当用含有1．0％ Cr2 O 3和0．04％ GO 的 GO-Cr(Ⅲ)<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>鞣制皮革时能够使皮革的收缩温度提高到118℃,Cr和 GO 的吸收率高达95％,比传统<span style=\"color:red\">铬</span>鞣剂可减少<span style=\"color:red\">铬</span>用量30％~50％,研究结果表明了 GO-Cr(Ⅲ)<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>可用作皮革鞣剂,具有用量少、鞣制效果好、吸收率高的特点,原因在于 GO-Cr(Ⅲ)<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>与胶原纤维有强的键合作用及纳米效应,研究结果对于实现少<span style=\"color:red\">铬</span>鞣制具有积极意义.","authors":[{"authorName":"吕生华","id":"5500b1a7-8067-4579-b562-175f41293deb","originalAuthorName":"吕生华"},{"authorName":"杨文强","id":"25352264-cbfc-4cee-bbf3-a9e77081e005","originalAuthorName":"杨文强"},{"authorName":"崔亚亚","id":"5d96cb86-6b1c-4e1b-979e-4a6811548e5a","originalAuthorName":"崔亚亚"},{"authorName":"周庆芳","id":"0456fac2-6a84-453e-b3dd-14c125af55d6","originalAuthorName":"周庆芳"},{"authorName":"孙世彧","id":"b97f4176-2147-451d-8c55-2113eca4960d","originalAuthorName":"孙世彧"}],"doi":"10.3969/j.issn.1001-9731.2015.07.017","fpage":"7081","id":"51ebf471-ef32-4b05-becf-e8db898cb40d","issue":"7","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"49a239c4-fd87-4d02-814d-3a148959be19","keyword":"氧化石墨烯","originalKeyword":"氧化石墨烯"},{"id":"d1531fec-acbb-4bd0-85cb-0c0f85e8c3c3","keyword":"<span style=\"color:red\">铬</span>鞣剂","originalKeyword":"铬鞣剂"},{"id":"941ac78b-f9dc-4ab0-b776-753d20d92946","keyword":"<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>","originalKeyword":"配合物"},{"id":"99b1dbc6-6bbf-4ebe-bbdb-19694b84e453","keyword":"收缩温度","originalKeyword":"收缩温度"}],"language":"zh","publisherId":"gncl201507017","title":"氧化石墨烯与<span style=\"color:red\">铬</span>(Ⅲ)<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>的制备与鞣制性能","volume":"","year":"2015"},{"abstractinfo":"将3种典型的氨基酸-水杨醛Schiff碱<span style=\"color:red\">铬</span>(III)<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>固载于介孔MCM-41上,制得非均相Schiff碱<span style=\"color:red\">铬</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>,用傅里叶变换红外光谱、紫外-可见光谱、X射线固体粉末衍射、N2吸附和元素分析对其结构进行了表征,并以30％H2O2为氧化剂,考察该<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>对环己烯环氧化反应的催化性能.结果表明,均相<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>非均相化后,其催化活性明显提高.在较优的反应条件下,环己烯转化率可达52.6％,环氧环己烷选择性为73.5％,且该非均相催化剂重复使用6次后,仍保持较高的催化活性.","authors":[{"authorName":"王晓丽","id":"11895036-26c4-487c-8d03-949f32a22911","originalAuthorName":"王晓丽"},{"authorName":"吴功德","id":"fa1d27d6-af67-4225-b308-db1598f39a28","originalAuthorName":"吴功德"},{"authorName":"王芳","id":"2d6e774c-adec-46af-ac51-e15c2fb8abd1","originalAuthorName":"王芳"},{"authorName":"魏伟","id":"fec3827c-08dc-4c5a-b1a1-2533815809f7","originalAuthorName":"魏伟"},{"authorName":"孙予罕","id":"67166a5e-3fa2-4eae-8464-b1ea738456e1","originalAuthorName":"孙予罕"}],"doi":"10.1016/S1872-2067(10)60272-0","fpage":"1812","id":"cc0d1fa3-d86a-450c-9c5c-74cd59bb7713","issue":"12","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"0a2c21d0-0642-4769-9d00-2b94a3dc12a1","keyword":"非均相","originalKeyword":"非均相"},{"id":"058f0e5e-f0eb-4bd4-9c5d-7fef56eca9c9","keyword":"氨基酸","originalKeyword":"氨基酸"},{"id":"04cd3838-e2c0-4c22-b7ad-7150f2c40107","keyword":"Schiff碱","originalKeyword":"Schiff碱"},{"id":"5bc7738e-4556-4613-aa21-bc527bbd71e9","keyword":"环己烯","originalKeyword":"环己烯"},{"id":"ed744fb0-a7a8-4fd6-abb3-cd7b06e06b3f","keyword":"环氧化","originalKeyword":"环氧化"}],"language":"zh","publisherId":"cuihuaxb201112006","title":"非均相Schiff碱<span style=\"color:red\">铬</span>(Ⅲ)<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>催化环己烯环氧化性能的研究","volume":"32","year":"2011"},{"abstractinfo":"将Cr(salen)<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>分别嫁接于介孔SiO2,MCM-41和SBA-15上制备成非均相Schiff碱<span style=\"color:red\">铬</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>,并用FT-IR,UV-Vis,XRD,N2吸附和元素分析等对非均相<span style=\"color:red\">铬</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>进行了表征.以30％的H2O2为氧化剂,以非均相<span style=\"color:red\">铬</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>为催化剂,在无有机溶剂、相转移催化剂和添加剂的条件下,研究了选择性催化氧化苯甲醇合成苯甲醛的反应.结果表明,非均相<span style=\"color:red\">铬</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>都表现出较好的催化性能.选择不同的介孔载体对非均相<span style=\"color:red\">铬</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>的催化性能有较大的影响,Cr(salen)/MCM-41<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>显示有最好的催化性能;在优化的反应条件下,苯甲醇转化率可达52.5％,苯甲醛选择性为100％,且该非均相<span style=\"color:red\">铬</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>重复使用4次后仍保持较好的催化性能.","authors":[{"authorName":"王晓丽","id":"2b0e49b8-1676-4c2e-9920-311ff8690ac8","originalAuthorName":"王晓丽"},{"authorName":"吴功德","id":"015508f0-6b97-4225-8ee5-9b89724e3d50","originalAuthorName":"吴功德"},{"authorName":"李军平","id":"42396524-ddb9-4dcf-bccc-64ac1228b0c9","originalAuthorName":"李军平"},{"authorName":"肖福魁","id":"45b5d652-5ae4-4d66-bc2d-4dee922082f9","originalAuthorName":"肖福魁"},{"authorName":"魏伟","id":"f9b3666c-b4d1-4f14-9850-86b888867148","originalAuthorName":"魏伟"},{"authorName":"孙予罕","id":"15851b5c-0b71-4ee8-a008-77ae77cda816","originalAuthorName":"孙予罕"}],"doi":"","fpage":"1101","id":"f14c199c-fa5a-4578-8ff5-dfc7e84b55db","issue":"12","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"e52012d1-96f7-41fa-ad86-51236c48ae56","keyword":"<span style=\"color:red\">铬</span>","originalKeyword":"铬"},{"id":"c7c57261-0d96-415e-88d1-a39f87491b47","keyword":"N,N-双水杨醛缩乙二胺配体","originalKeyword":"N,N-双水杨醛缩乙二胺配体"},{"id":"09d7fb8e-5e9b-4e35-a6f2-4d54bfa72fa1","keyword":"介孔载体","originalKeyword":"介孔载体"},{"id":"079ae1ee-4f5b-4665-8f6d-b26739dab3c6","keyword":"非均相<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>","originalKeyword":"非均相配合物"},{"id":"b73d3216-391e-4732-8cf8-8115476b0cbd","keyword":"席夫碱","originalKeyword":"席夫碱"},{"id":"e67a48fd-3490-42d8-8387-3a205e1318d5","keyword":"苯甲醇","originalKeyword":"苯甲醇"},{"id":"9c833f2d-db31-42fe-a949-4d68d2286591","keyword":"选择性氧化","originalKeyword":"选择性氧化"},{"id":"7aade908-7fa8-46ea-97ad-b5e8c3686daa","keyword":"苯甲醛","originalKeyword":"苯甲醛"}],"language":"zh","publisherId":"cuihuaxb200712017","title":"介孔载体嫁接的Schiff碱<span style=\"color:red\">铬</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>催化氧化苯甲醇合成苯甲醛","volume":"28","year":"2007"},{"abstractinfo":"以对苯二甲酸根(TPHA)为桥联配体.分别端接4.4＇-二甲基-2.2＇-联吡啶(Me 2bpy)，2.9-二甲基-1.10-邻菲哕啉(Me2phen)和5-氯-1，10-邻菲哕啉(Cl-phen).合成了3种新的双核<span style=\"color:red\">铬</span>(Ⅲ)<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>[Cr2-(TPHA)(Me2bpy)4](NO3)4(1)，[Cr2(TPHA)(Me2phen)4](NO3)4(2)和[Cr 2(TPHA)(Clphen)4](N)3)4(3).经元素分析、摩尔电导和磁性测定以及红外光谱和电子光谱等手段，推定这些<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>具有TPHA桥联双核<span style=\"color:red\">铬</span>(Ⅲ)结构，其中，每个<span style=\"color:red\">铬</span>(Ⅲ)离子处于畸变八面体配位环境.测定了<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>(1)的变温磁化率(4～300 K)，其数值用最小二乘法和从自旋Hamiltonian算符(H=-2JS^1S^2)导出的磁方程拟合，求得交换积分为-2.98 cm-1，结果表明双核<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>中金属离子间存在弱的反铁磁自旋交换作用.","authors":[{"authorName":"景志红","id":"8964da6f-a220-481f-ae9a-36957d1e50d0","originalAuthorName":"景志红"},{"authorName":"李延团","id":"a4553f45-000d-47ba-a07a-894c1fc15e23","originalAuthorName":"李延团"},{"authorName":"廖代正","id":"0ba95acc-bb8d-45a3-a713-9e905b030cfa","originalAuthorName":"廖代正"}],"doi":"10.3969/j.issn.1000-0518.2001.02.004","fpage":"100","id":"7a62bc6f-1e6d-4743-9723-af260092d707","issue":"2","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"544a2776-bc6c-4c61-86fe-6860811635be","keyword":"对苯二甲酸,双核<span style=\"color:red\">铬</span>(Ⅲ)<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>,合成,磁性","originalKeyword":"对苯二甲酸,双核铬(Ⅲ)配合物,合成,磁性"}],"language":"zh","publisherId":"yyhx200102004","title":"对苯二甲酸根桥联的双核<span style=\"color:red\">铬</span>(Ⅲ)<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>的合成与磁性","volume":"18","year":"2001"},{"abstractinfo":"银镀层存放和装机2～3个月后就会发生变色,降低银层的性能.分析了银层变色的原因,提出了相应的无<span style=\"color:red\">铬</span>防银变色工艺,介绍了其防变色效果,并对防变色<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>膜的性能、组成和结构进行了研究.","authors":[{"authorName":"方景礼","id":"0ed9800c-7bdf-4814-93db-5ec395d8bead","originalAuthorName":"方景礼"},{"authorName":"方欣","id":"5d435ef2-ab88-4b9e-aebd-f9f5c30a90c5","originalAuthorName":"方欣"}],"doi":"10.3969/j.issn.1001-1560.2007.10.026","fpage":"85","id":"0a8abae2-4d22-4942-8846-90930dd86b15","issue":"10","journal":{"abbrevTitle":"CLBH","coverImgSrc":"journal/img/cover/CLBH.jpg","id":"7","issnPpub":"1001-1560","publisherId":"CLBH","title":"材料保护"},"keywords":[{"id":"14b8769f-9b9d-4386-b15d-149b41063564","keyword":"银镀层","originalKeyword":"银镀层"},{"id":"dc6433e1-9a41-4f27-8832-1ceae075ffb7","keyword":"变色","originalKeyword":"变色"},{"id":"30f61ea9-ac6c-4a85-87a3-5496ca286b77","keyword":"防变色","originalKeyword":"防变色"},{"id":"8a5ae1e3-aa9f-41b6-87c6-a781929d81c7","keyword":"<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>","originalKeyword":"配合物"},{"id":"fbee93b8-69ce-442a-9aff-5e602f348121","keyword":"表面膜","originalKeyword":"表面膜"}],"language":"zh","publisherId":"clbh200710026","title":"金属表面<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>保护膜述评(Ⅱ)——银的防变色<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>膜","volume":"40","year":"2007"},{"abstractinfo":"综述了近10余年来稀土<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>药物研究进展以及发展趋势.研究现状反映出参与药物合成的稀土元素以镧、镨、钕和钐为主,配体以杂环化合<span style=\"color:red\">物</span>为多,药理作用研究主要集中在抗肿瘤、抗病毒以及抗菌等方面.在此基础上指出了稀土黄酮类<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>有望在抗骨质疏松症作用方面表现出良好的前景.","authors":[{"authorName":"张金超","id":"550689fa-29f0-4478-9dc7-b4c2385d3bb7","originalAuthorName":"张金超"},{"authorName":"杨梦苏","id":"0a096326-e0cc-4864-8fdd-642fbcef9204","originalAuthorName":"杨梦苏"}],"doi":"10.3969/j.issn.0258-7076.2005.06.024","fpage":"919","id":"917b74f0-3c4a-49bc-8d15-6128968d046d","issue":"6","journal":{"abbrevTitle":"XYJS","coverImgSrc":"journal/img/cover/XYJS.jpg","id":"67","issnPpub":"0258-7076","publisherId":"XYJS","title":"稀有金属"},"keywords":[{"id":"c624032b-6179-42d7-909a-9b943335eac8","keyword":"稀土<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>","originalKeyword":"稀土配合物"},{"id":"5d3726bc-e3a4-4bd5-8293-70e55125cc3b","keyword":"药物合成","originalKeyword":"药物合成"},{"id":"56488551-9d64-4feb-af25-9b98353e6a3f","keyword":"药理作用","originalKeyword":"药理作用"}],"language":"zh","publisherId":"xyjs200506024","title":"稀土<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>药物研究进展","volume":"29","year":"2005"},{"abstractinfo":"铜和铜合金具有优良的导电性、导热性和可焊性,是目前应用最广的金属材料之一.但它在潮湿工业大气中很容易发生腐蚀变色,变色膜会降低铜的各种性能,严重影响它们的使用效果和寿命.评述了铜与铜合金的腐蚀变色,无<span style=\"color:red\">铬</span>防铜变色工艺以及防铜变色<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>膜的组成与结构.","authors":[{"authorName":"方景礼","id":"0320641c-ccdb-46ee-b7b8-3e7ebf30b158","originalAuthorName":"方景礼"},{"authorName":"方欣","id":"45aa4eed-4871-49fb-b9cd-dbd4d4ff844d","originalAuthorName":"方欣"}],"doi":"10.3969/j.issn.1001-1560.2007.11.026","fpage":"76","id":"3f4c6be3-3e1f-490d-bd99-163ed3d540b2","issue":"11","journal":{"abbrevTitle":"CLBH","coverImgSrc":"journal/img/cover/CLBH.jpg","id":"7","issnPpub":"1001-1560","publisherId":"CLBH","title":"材料保护"},"keywords":[{"id":"33ea96b4-f89c-493b-b3be-c18eaa7763dc","keyword":"铜","originalKeyword":"铜"},{"id":"ed7b5e70-05bf-4e1b-a954-d1befd147dfd","keyword":"铜镀层","originalKeyword":"铜镀层"},{"id":"f8485a6a-0d67-4a61-bcf5-c4ddaa5d9b90","keyword":"变色","originalKeyword":"变色"},{"id":"aa2ec660-d926-4140-bc69-650c9fe68aec","keyword":"防变色","originalKeyword":"防变色"},{"id":"126a3979-16ad-4be1-a22b-78a42376bc49","keyword":"<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>","originalKeyword":"配合物"},{"id":"549f0153-7247-4a07-9833-f9cc189ef7e5","keyword":"表面膜","originalKeyword":"表面膜"}],"language":"zh","publisherId":"clbh200711026","title":"金属表面<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>保护膜述评(Ⅱ)——铜及铜合金的防变色<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>膜","volume":"40","year":"2007"},{"abstractinfo":"采用一种新方法制备无水稀土<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>,其中一步法直接合成三氯化铕的绝对无水乙醇溶液.在稀土<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>中引入带胺基的功能配体,使其与三氯化铕反应合成了两种两端含有胺基具有缩聚活性的<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>.以元素分析、红外光谱和紫外光谱对<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>的组成和结构进行表征,并以摩尔电导和荧光光谱对<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>的性质进行研究,结果表明,在DMF中<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>可作为聚合单体应用;粉末状态下,<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>具有高的荧光强度,荧光单色性好.","authors":[{"authorName":"周新木","id":"72fff745-819c-4487-98f1-3708e1ea954f","originalAuthorName":"周新木"},{"authorName":"谈宏宇","id":"e6ff77ee-bb43-43bf-a67f-b95db8c4134c","originalAuthorName":"谈宏宇"},{"authorName":"赵光好","id":"e95942c6-0bbd-489d-8234-8db8c423901d","originalAuthorName":"赵光好"},{"authorName":"徐招弟","id":"873747ab-0170-4dbd-9db5-d575927c639d","originalAuthorName":"徐招弟"},{"authorName":"刘风兰","id":"3e0fd92e-7b43-43c6-8922-cb7bbc5d2b33","originalAuthorName":"刘风兰"}],"doi":"10.3969/j.issn.1004-0277.2006.02.009","fpage":"30","id":"1d611456-16c1-4031-8fe1-3febcd30b555","issue":"2","journal":{"abbrevTitle":"XT","coverImgSrc":"journal/img/cover/XT.jpg","id":"65","issnPpub":"1004-0277","publisherId":"XT","title":"稀土"},"keywords":[{"id":"9c08750d-11a4-4879-bd53-be266bffa757","keyword":"稀土<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>单体","originalKeyword":"稀土配合物单体"},{"id":"a3c67f8b-f92d-47d0-a704-5f49b859d356","keyword":"共缩聚","originalKeyword":"共缩聚"},{"id":"c47984da-c0db-4a3c-bcfc-e8e8722ae7d0","keyword":"荧光性质","originalKeyword":"荧光性质"}],"language":"zh","publisherId":"xitu200602009","title":"缩聚活性铕<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>的合成与表征","volume":"27","year":"2006"}],"totalpage":4207,"totalrecord":42067}